For A Proper Pretzel Crust, Count On Chemistry And Memories (2024)

Bavarian pretzels baked at the Goetz bakery in Taufkirchen, Germany, for the Oktoberfest beer festival. Miguel Villagran/Getty Images hide caption

toggle caption

Miguel Villagran/Getty Images

For A Proper Pretzel Crust, Count On Chemistry And Memories (2)

Bavarian pretzels baked at the Goetz bakery in Taufkirchen, Germany, for the Oktoberfest beer festival.

Miguel Villagran/Getty Images

As Oktoberfest starts in Munich every September, my mom starts making pretzels in Michigan. She says the soft pretzels in the U.S. aren't like what she was used to in Germany, and if she's going to be hosting a backyard Oktoberfest, her food should be authentic.

As a kid I watched the flour, yeast and salt whirl together in a food processor until suddenly congealing into a sticky ball. I liked to put my hand on the risen dough and pat it like a warm, soft belly. I helped dip the pretzels into something bubbling in the pot on the stove, careful not to touch the rolls after they were out of the bath.

That's because that bath was actually a caustic alkaline solution. Traditional Bavarian pretzels are dipped in a lye solution before they are baked. Lye, also known as sodium hydroxide, is essentially the same stuff that's used to make soap and clean drains. It can even dissolve glass.

But it's also what makes a good pretzel, says Wolfgang Büchler, owner of the Heidelberg Pastry Shoppe in Arlington, Va.. The shop is named after his German hometown.

The Salt

100 Years Ago, Maillard Taught Us Why Our Food Tastes Better Cooked

Büchler's employees snap on rubber gloves before dipping their handmade pretzels in the lye solution before baking. The solution, which Büchler imports from Germany, doesn't look like much; it's a dingy brown color. But it changes the pretzel's flavor and color in a way you can't really explain until you taste it, he says.

Lye can be toxic in high concentrations, but is also commonly used for curing foods like lutefisk. Most bakers use food-grade lye, which is the chemical equivalent of drain cleaner, but is produced and packaged in a clean, regulated way.

Since the lye dip is heavily diluted and the pretzel is baked after dipping, it won't kill you. Nonetheless, Della Limbert, a tour guide at Julius Sturgis Pretzel Bakery in Lititz, Pa., says the Julius Sturgis factory prefers a less risky mix of hot water and special baking soda flakes instead.

The Salt

Cookie-Baking Chemistry: How To Engineer Your Perfect Sweet Treat

Those flakes are more caustic than the baking soda you buy at the grocery store, but not nearly as caustic as lye. They essentially do the same job.

In case you were wondering, George Preti, a chemist at the Monell Chemical Senses Center, says baking soda maxes out at about 9.5 on the pH scale (which measures how acidic a substance is), while lye can get up to 14 (the highest ranking).

The dipping process is an important part of pretzel baking — it doesn't matter if it's a Philly-style pretzel (shaped like an elongated figure eight) or a hard pretzel you'd find at a gas station (baked twice as long).

"If you don't put a browning agent on the product, the pretzel is white," says Tony Tonelli, owner of Center City Soft Pretzel Co. in Philadelphia. "If you let it go into the oven white, it'll come out of the oven white."

That's because the alkaline lye bath affects the way the Maillard reaction plays out when the pretzel bakes, says Bread Science author Emily Buehler. The Maillard process is integral to all bread baking — it shapes the way the crust forms and tastes. In the case of the pretzel, the Maillard reaction is responsible for the deep brown crust, crunchy arms and distinctive taste.

At its most basic, the Maillard process is a heat-activated reaction between small sugars and amino acids. Dipping dough in lye alters the ratio between sugar and protein, because lye breaks proteins present in the dough into smaller bits. Those are the small amino acids that then combine with sugars in the dip to create the flavor compounds at the pretzel's crust.

My mom always told me that lye was what made a German pretzel different from an American pretzel, but that doesn't necessarily seem to be the case.

She doesn't even use real lye, she just puts in massive amounts of baking soda to make a stronger solution. But she still insists that she hasn't found a good Oktoberfest pretzel in the U.S.

Büchler says he tried buying lye in the states, but it doesn't live up to what he imports from Germany for his pretzels.

And those commercial soft pretzels? Forget about it. "You get the same pretzel in a Philadelphia sports stadium that you'll get in the San Francisco stadium, in a Buffalo sports stadium, New England — you'll still get the same pretzel, which is a three-ring, frozen pretzel," Tonelli laments.

My mom adds that the time the pretzel stays in the bath and the heat of the oven are also crucial. But maybe it's also partly that fresh-baked pretzels are a form of comfort food, reminding you of home, whether it's Philadelphia or Germany.

If you want to make real Bavarian pretzels, here's my mom's recipe. It has the original Metric system measurements, so grab a kitchen scale for this one.

Nina Goebel's Bavarian Pretzels

500 grams flour
1 packet rapid rise yeast
1 teaspoon salt
200-250 milliliters hot water (almost boiling)
60 grams baking soda
1 liter of water
Coarse kosher salt (for sprinkling just before baking)

Preheat oven to 400 F (200 C)

In a food processor with dough-blade attachment, mix yeast, hot water, salt and flour. Place into a bowl and cover with a moist kitchen towel. Let the dough rise for about two hours.

Form dough into pretzels, rolls or whatever shape you prefer. (Note: The actual pretzel shape is really difficult to get right; rolls are far easier)

Mix baking soda into water and bring to a boil. Dip pretzels for 30 seconds to a minute, turn and leave in the solution for another 30 seconds. Take them out carefully with a slotted spoon and dry off, patting with a paper towel. Place onto a cookie sheet lined with parchment paper. Sprinkle with salt.

Bake for about 14-20 minutes, until "nice and brown."

Important: Avoid touching the dough after dipping it into the baking soda mixture, and keep it off of aluminum surfaces. It's not lye, but it's still corrosive.

For A Proper Pretzel Crust, Count On Chemistry And Memories (2024)

FAQs

For A Proper Pretzel Crust, Count On Chemistry And Memories? ›

For A Proper Pretzel Crust, Count On Chemistry And Memories : The Salt The key to getting a good soft pretzel to brown properly is to dip it in a lye solution, the same stuff that's used to make soap.

What chemical is used in pretzels? ›

Lye is primarily used to make pretzels, and it's the reason for their unmistakable shiny, mahogany color. To prepare, shaped pretzels are dipped in a lye bath, then baked in the oven.

Is baking pretzels a chemical change? ›

Have students recall that baking powder, the chemical leavener used in the Whole Wheat Soda Bread, produces CO2 to make bread rise. Explain that for the Soft Pretzels we will use a biological leavener, yeast, to create the chemical reaction that will make our pretzels rise.

What is the characteristic step involved in soft pretzel baking that gives them their characteristic taste? ›

Traditionally, pretzels are dipped in a lye bath before baking. Lye, or sodium hydroxide (NaOH), is a highly basic (alkaline) compound and dipping raw, unbaked pretzels into its solution promotes browning and gives them their characteristic flavour, chewy texture and dark colour.

What is the Maillard reaction in pretzels? ›

Pretzels brown due to complex reactions called Maillard reactions. In the case of the pretzels, heat from the oven acted as a catalyst for the reaction of reducing sugars with free amino groups of amino acids that were part of protein chains.

What is the science behind the pretzel? ›

In the case of the pretzel, the Maillard reaction is responsible for the deep brown crust, crunchy arms and distinctive taste. At its most basic, the Maillard process is a heat-activated reaction between small sugars and amino acids.

What elements are in pretzels? ›

Pretzels are a type of bread typically made from wheat or rye flour and a few other ingredients, such as yeast, sugar, salt, water, and butter.

What is the secret ingredient which makes a pretzel taste like a pretzel? ›

The answer lies in a brief dip in an alkaline water bath before baking. This bath essentially gelatinizes the outside of the pretzel, preventing it from fully “springing” during baking (as bread does) and giving pretzels their signature chewy crust. It also gives them their unique and indelible “pretzel” flavor.

What type of chemical reaction is baking? ›

Sugar Reacts With Heat and Proteins to Create the Perfect Crust. You know your cake is done baking when you pull it out of the oven and see that perfect golden brown crust on top. That sweet, toasted crust is the result of a chemical reaction between sugars and proteins called the Maillard reaction.

What is the alkaline solution for pretzels? ›

Pretzels get their signature dark colour, slightly metallic flavour and chewy-leathery exterior from being dipped in a solution of water and food-grade lye, a strong alkaline ingredient. In the kitchen, baking soda is far more common, but it's a weaker alkali, so doesn't produce quite as dramatic an effect.

What makes a pretzel extra dark? ›

The only difference is that we bake them in our stone hearth oven for a bit longer until they have a nearly black finish. Whether you enjoy them on their own or mix and match them with our other handcrafted pretzel products, our extra dark pretzels for sale are sure to hit the spot when you give them a chance.

Why do my homemade pretzels taste weird? ›

If your pretzels have any sort of a metallic, bitter taste, it all comes down to the baking soda bath.

Why do my pretzels not brown? ›

If you don't dunk your pretzels in the bath before baking, it's going to take much longer for that browning to occur. And by the time your pretzels get as dark and crackly as you want them to, the interior texture is going to be destroyed, and they're frankly going to be just gross.

What chemical compound is used to make pretzels? ›

Then I dug a little deeper and started reading about soft pretzels, and I learned that the key to making them authentic is a little something called NaOH. Otherwise known as sodium hydroxide, and otherwise known as caustic soda, or lye, or highly poisonous chemicals that are used to clean out plugged-up drains.

How does baking soda work for pretzels? ›

After you boil the pretzels in the baking soda water, you place them in the oven. The heat from the oven interacts with the baking soda molecules coating the pretzels. This causes the molecules to react with one another, increasing the alkalinity of the outside of the pretzel.

Why is lye used to make pretzels? ›

The Truth About Lye

It imparts that unique pretzel smell and taste by inhibiting the creation of typical baked-good aroma compounds while spurring the formation of others and also adds unmistakable mineral flavor. And it gels surface starch, so the pretzels bake up smooth and shiny.

Is lye still used for pretzels? ›

Lye is the secret ingredient that gives pretzels their characteristic look and taste. Without lye, you have a breadstick.

What is the secret ingredient in pretzels? ›

According to King Arthur Baking, lye and caustic sodas are used in the process of baking pretzels because lye's reaction to the pretzels, much like baking soda, gives them that chewy texture, light interior, and brown crust.

Are pretzels dipped in caustic soda? ›

3.1.

Caustic soda serves a vital purpose in the pretzel making process. When pretzels are dipped in a solution of caustic soda and water before baking, it helps achieve their characteristic chewiness and distinctive flavor.

What solution are pretzels dipped in? ›

Traditional German pretzels are first dipped in a 3% to 4% lye-to-water bath before baking. Pretzel purists often argue a pretzel isn't really a pretzel unless lye is used.

Top Articles
Latest Posts
Article information

Author: Kareem Mueller DO

Last Updated:

Views: 6505

Rating: 4.6 / 5 (46 voted)

Reviews: 93% of readers found this page helpful

Author information

Name: Kareem Mueller DO

Birthday: 1997-01-04

Address: Apt. 156 12935 Runolfsdottir Mission, Greenfort, MN 74384-6749

Phone: +16704982844747

Job: Corporate Administration Planner

Hobby: Mountain biking, Jewelry making, Stone skipping, Lacemaking, Knife making, Scrapbooking, Letterboxing

Introduction: My name is Kareem Mueller DO, I am a vivacious, super, thoughtful, excited, handsome, beautiful, combative person who loves writing and wants to share my knowledge and understanding with you.